Publication

68. Naphthalene diimide-Annulated Heterocyclic Acenes: Synthesis, Electrochemical and Semiconductor Properties and their Multifaceted Applications

 Abhishek Bhardwaj, Pratik Dewangan, Ch Mudasar Hussain, and P. Mukhopadhyay*

Chem. Eur. J. 2024 e202400208 

https://doi.org/10.1002/chem.202400208

 

67. Synthesis of cyanated Naphthalene diimide-Hydroazaacenes: Amphoteric-redox, low-lying LUMO, Bright-red emission, aggregation and aromaticity evaluation 

 Devendra krishna Kumar M. S and P. Mukhopadhyay*

dyes and pigments 2024. 223,111955

https://doi.org/10.1016/j.dyepig.2024.111955  

66. Synthesis, optical and redox attributes of core-/bay-substituted thionated NDIs, PDIs and their diverse radical anions

Kalyanashis Mandal, Devendra Yadav, Poonam Saini and P. Mukhopadhyay*

J. Mater. Chem. C. 2023. Advance Article.

https://doi.org/10.1039/d3tc02187d  

65. A Folded π-system with Supramolecularly Oriented Dipoles: Single-Component Piezoelectric Relaxor with NLO-Activity 

Soumi De, D. Asthana, Chinthakuntla Thirmal, Sudhir K. Keshri, Ram Krishna Ghosh, Geeta Hundal, Raju Kumar, Satyendra Singh, Ratnamala Chatterjee and  P. Mukhopadhyay*

Chemical Science, 2023.

https://doi.org/10.1039/D2SC06141D. 

64. A Highly Contorted Push-Pull Naphthalenediimide Dimer and Evidence of Intramolecular Singlet Exciton Fission

D. Bansal, A. Kundu, V. P. Singh, A. K. Pal, A. Datta * , J. Dasgupta * and P. Mukhopadhyay *

Chemical Science, 2022, Advance Article.

https://doi.org/10.1039/D2SC04187A

2022 Chemical Science Hot Article Collection

63. Synthesis and Properties of Electron‐Deficient and Electron‐Rich Redox‐Active Ionic π‐Systems

S. Chorol, P. Saini and P. Mukhopadhyay*

The Chemical Record, 2022, e202200172.

https://doi.org/10.1002/tcr.202200172

Invited: A special collection highlighting Materials Chemistry in India

62. Synthesis of a Highly Electron-Deficient, Water-Stable, Large Ionic Box: Multielectron Accumulation and Proton Conductivity.

J. Shukla, R. Illathvalappil, S. Kumar, S. Chorol, A. Pandikassala, S. Kurungot, and P. Mukhopadhyay*

Org. Lett. 2022, 24, 3038–3042.

https://doi.org/10.1021/acs.orglett.2c00993

61. Acridine-Peptide Conjugated Nanofiber Assembly Triggers Stimuli-Free Immobilization of Crude Oil and Read-Out by Turn-On Emission.

D. Asthana*, N. Patti, and P. Mukhopadhyay*

ChemNanoMat. 2022, 8, e202200220.

doi.org/10.1002/cnma.202200220

Invited: A special collection highlighting Materials Chemistry in India

60. DNA damage, cell cycle perturbation and cell death by naphthalene diimide derivative in gastric cancer cells.

S. K. Gurung, S. Kumari, S. Dana, K. Mandal, S. Sen, P. Mukhopadhyay, N. Mondal.

Chemico-Biological Interactions, 2022, 358, 109881.

https://doi.org/10.1016/j.cbi.2022.109881

59. Naphthalenediimides with High Fluorescence Quantum Yield: Bright-Red, Stable and Responsive Fluorescent Dyes.

S. K. Keshri, K. Mandal, Y. Kumar, D. Yadav, P. Mukhopadhyay*

Chem. Eur. J. 2021, 27, 6954-6962.

https://doi.org/10.1002/chem.202100020

58. A Facile Access to Multi-State Redox-Active, Push-Pull Naphthalenediimides: Panchromatic Radical Anions and Supramolecular Networks.

D. Bansal, P. Mukhopadhyay*

J. Mater. Chem. C. 2021, 9, 3948-3956.

DOI: 10.1039/D0TC05702A

57. Synthesis of Stable, High-SOMO Zwitterionic Radicals: Enabling Electron Transfer Between Naphthalenediimides.

J. Shukla, S. Kumar, Rustam, P. Mukhopadhyay*

Org. Lett. 2020, 22, 6229-6233. (Cover Article)

doi.org/10.1021/acs.orglett.0c01263

56. Halogen Bonded Assemblies of Arylene-imides and -diimides: Insight from Electronic, Structural and Computational studies.

K. Mandal, D. Bansal, Y. Kumar, Rustam, J. Shukla, P. Mukhopadhyay*

Chem. Eur. J. 2020, 26, 10607-10619.

https://doi.org/10.1002/chem.202001706

55. Synthesis of Novel Ciprofloxacin-Based Hybrid Molecules toward 2 Potent Antimalarial Activity. 

S. Dana, P. Valissery, S. Kumar, S. K. Gurung, N. Mondal, S. K. Dhar,* P. Mukhopadhyay*    

ACS Med. Chem. Lett. 2020, 11, 1450–1456.

https://dx.doi.org/10.1021/acsmedchemlett.0c00196

54. Molecular and Supramolecular Multiredox Systems.

J. Shukla, V. P. Singh, P. Mukhopadhyay *

ChemistryOpen 2020, 9, 304-324.

(Invited article: Special Collection on Functional Supramolecular Systems)

https://doi.org/10.1002/open.201900339

53.  Doubly-Zwitterionic, Di-reduced, Highly Electron-Rich, Air-Stable Naphthalenediimides: Redox-Switchable Islands of Aromatic-Antiaromatic States.

Kumar, S., Shukla, J., Mandal, K., Kumar, Y., Prakash, R., Ram, P., Mukhopadhyay, P.*

Chem. Sci. 2019, 10, 6482-6493.

DOI: 10.1039/C9SC00962K

52. Synthesis of Functionalized Naphthalene Diimides and their Redox Properties .

J. Shukla,  P. Mukhopadhyay *

Eur. J. Org. Chem. 2019, 7770-7786. (Invited article) and (Cover article).


(Invited article: Special Collection on Functional Supramolecular Systems)

https://doi.org/10.1002/open.201900339

51. Synthesis and Isolation of a Stable Perylenediimide Radical Anion and Its Exceptionally Electron-Deficient Precursor

Y. Kumar, S. Kumar, D. Bansal, P. Mukhopadhyay*

Org. Lett. 2019, 21, 2185-2188.

https://doi.org/10.1021/acs.orglett.9b00490

50. Ionic Assembly, Anion‐π, Magnetic and Electronic Attributes of Ambient Stable Naphthalenediimide Radical Ions

S. Kumar, V. Malik, J. Shukla, Y. Kumar, D. Bansal, R. Chatterjee, P. Mukhopadhyay*

Chem. Eur. J. 2019, 25, 4740-4750.

https://doi.org/10.1002/chem.201805978

49. Core-insertion of palladium in naphthalenediimides: Opto-electronic properties, structural insights and coupling studies

D. Bansal, Y. Kumar, S. Kumar, K. Mandal, G. Hundal, P. Mukhopadhyay*

Inorg. Chim. Acta, 2019, 486, 185-192 (Invited Article: Special Issue).

https://doi.org/10.1016/j.ica.2018.09.077

48. Downregulation of c-Myc and p21 expression and induction of S phase arrest by naphthalene diimide derivative in gastric adenocarcinoma cells

S. Gurung, S. Dana, K. Mandal, P. Mukhopadhyay, N. Mondal*

Chemico-biological interactions, 2019, 304, 106-123.

https://doi.org/10.1016/j.cbi.2019.02.010

47. Isolation of Tetracyano‐Naphthalenediimide and Its Stable Planar Radical Anion

Y. Kumar, S. Kumar, K. MandalP. Mukhopadhyay*

Angew. Chem. Int. Ed. 2018, 57, 16318-16322 (Hot Paper and Cover Article).

doi: 10.1002/anie.201807836

46. Buchwald-Hartwig Coupling at the Naphthalenediimide Core: Access to Dendritic, Panchromatic NIR Absorbers with Exceptionally Low Band Gap

J. Shukla, M. R. Ajayakumar, P. Mukhopadhyay*

Org. Lett. 2018, 20, 7864-7868.

https://doi.org/10.1021/acs.orglett.8b03408

45. Ambient stable naphthalenediimide radical ions: synthesis by solvent-free, sonication, mechanical grinding or milling protocols

S. Kumar, P. Mukhopadhyay*

Green Chem., 2018, 20, 4620-4628 (Cover Article).

https://doi.org/10.1039/C8GC01614C

44. Electron sponge from naphthalenediimide–viologen conjugates: water-stable, highly electron-deficient polyions with 1 V potential window

 J. Shukla, M. R. Ajayakumar, Y. Kumar, P. Mukhopadhyay*

Chem. Commun. 2018, 54, 900-903.

https://doi.org/10.1039/C7CC09372A

43. Electron-poor arylenediimides

S. Kumar, J. Shukla, Y. Kumar, P. Mukhopadhyay*

Org. Chem. Front. 2018, 5, 2254-2276.

https://doi.org/10.1039/C8QO00256H

42. Appending Diverse π‐Extended Acceptors with Tetrathiafulvalene/Dithiafulvalene Donors: Multistate Redox Properties, Radical Ion Generation, and Mid‐IR‐Absorbing Mixed Valence States

 S. K. Keshri, D. Asthana, S. Chorol, Y. Kumar, P. Mukhopadhyay*

Chem. Eur. J. 2018, 24, 1821-1832 (Frontispiece Article).

https://doi.org/10.1002/chem.201880865

41. Role Reversal of the Carboxylate Group from Coordination to Hydrogen Bonding Only, in Structurally Diverse Metal-2-amino, 5-Nitro-benzoates: A First Report

A.    K. Jassal, B. S. Sran, K. Mandal, P. Mukhopadhyay, G. Hundal*

Crystal Growth & Design, 2018, 18, 4737-4748.

https://doi.org/10.1021/acs.cgd.8b00771 

40. Ambient Water‐Stable Dianionic Electron Donors: Intramolecular Noncovalent Conduits Assist Charge Delocalization

S. K. Keshri, S. Kumar, K. Mandal, P. Mukhopadhyay*

Chem. Eur. J. 2017, 23, 11802-11809 (Frontispiece Article).

https://doi.org/10.1002/chem.201701868

39. Synthesis of octabromoperylene dianhydride and diimides: evidence of halogen bonding and semiconducting properties

Y. Kumar, S. Kumar, S. K. Keshri, J. Shukla, S. S. Singh, T. S. Thakur, M. Denti, A. Fachetti,* P.  Mukhopadhyay*

Org. lett. 2016, 18, 472-475.

https://doi.org/10.1021/acs.orglett.5b03513

38. Recent Advances in Organic Radicals and Their Magnetism

S. Kumar, Y. Kumar, S. K. Keshri, P. Mukhopadhyay*

 Magnetochemistry, 2016, 2, 42 (Invited Review).

https://doi.org/10.3390/magnetochemistry2040042

37. Design, Synthesis and Evaluation of Bifunctional Acridinine−Naphthalenediimide Redox-Active Conjugates as Antimalarials

S. Dana, S. K. Keshri, J. Shukla, K. S. Vikramdeo, N. Mondal, P. Mukhopadhyay*, S. K. Dhar*

    ACS Omega, 2016, 1, 318-333.

https://doi.org/10.1021/acsomega.6b00060

36. Assorted morphosynthesis: access to multi-faceted nano-architectures from a super-responsive dual π functional amphiphilic construct

D. Asthana, J. Shukla, S. Dana, V. Rani, M.R. Ajayakumar, K. Rawat, K. Mandal, P. Yadav, S. Ghosh, P.  Mukhopadhyay*

Chem. Comm. 2015, 51, 15237-15240 (Cover Article).

https://doi.org/10.1039/C5CC05198C

35. Extraordinary stability of naphthalenediimide radical ion and its ultra-electron-deficient precursor: strategic role of the phosphonium group

 S. Kumar, M. R. Ajayakumar, G. Hundal, P. Mukhopadhyay*

J. Am. Chem. Soc. 2014, 136, 12004-12010.

https://doi.org/10.1021/ja504903j

34. Self-assembly characteristics of a multipolar donor-acceptor–based bis-pyrene integrated molecular tweezer

 D. Asthana, G. Hundal, P. Mukhopadhyay*

J. Chem. Sci. 2014, 126, 1331-1336 (Invited Article, Special issue on Chemical Crystallography).

https://doi.org/10.1007/s12039-014-0687-8

33. Potent Antimalarial Activity of Acriflavine In Vitro and In Vivo

S. Dana, D. Prusty, D. Dhayal, M. K. Gupta, A. Dar, S. Sen, P. Mukhopadhyay, T. Adak, S. K. Dhar*

ACS chem. Biol. 2014, 9, 2366-2373.

https://doi.org/10.1021/cb500476q

32. Self-assembly patterns of steroid-based all-organic ferroelectrics: valuable insights from the single-crystals derived from an organogel and solution

D. Asthana, S. K. Keshri, G. Hundal, G. Sharma, P. Mukhopadhyay*

Cryst. Eng. Comm. 2014, 16, 4861-4866 (Invited Article, Themed issue on International Year of   Crystallography).

https://doi.org/10.1039/C4CE00013G

31. Single electron transfer-driven multi-dimensional signal read-out function of TCNQ as an “Off-the-Shelf” detector for cyanide

M. R. Ajayakumar, K. Mandal, K. Rawat, D. Asthana, R. Pandey, A. Sharma, S. Yadav, S. Ghosh, P.  Mukhopadhyay*

ACS applied materials & interfaces, 2013, 5, 6996-7000 (Cover Article).

https://doi.org/10.1021/am4011176

30. Urea-based constructs readily amplify and attenuate nonlinear optical activity in response to H-bonding       and anion recognition

D. Asthana, R. Pandey, P. Mukhopadhyay*

Chem. Commun. 2013, 49, 451-453 (Cover Article).

https://doi.org/10.1039/C2CC36631B

29. A tetrastable naphthalenediimide: anion induced charge transfer, single and  double electron transfer for combinational logic gates

 M. R. Ajayakumar, G. Hundal, P. Mukhopadhyay*

Chem. Commun. 2013, 49, 7684-7686 (Cover Article).

https://doi.org/10.1039/C3CC43280G

28. NTCDA–TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

D. Asthana, M. R. Ajayakumar, R. P. Pant, P. Mukhopadhyay*

Chem. Commun. 2012, 48, 6475-6477 (Cover Article).

https://doi.org/10.1039/C2CC31274C

27. Core-modified naphthalenediimides generate persistent radical anion and cation: New panchromatic NIR probes

M. R. Ajayakumar, D. Asthana, P. Mukhopadhyay*

Org. lett. 2012, 14, 4822-4825.

https://doi.org/10.1021/ol302140x

26.. Assemblies of perylene diimide derivatives with melamine into luminescent hydrogels

P. K. Sukul, D. Asthana, P. Mukhopadhyay, D. Summa, L. Muccioli, C. Zannoni, D. Beljonne,*  A. E.         Rowan,* S. Malik*

Chem. Commun. 2011, 47, 11858-11860.

https://doi.org/10.1039/C1CC14189A

25. An all-organic steroid–D–π-A modular design drives ferroelectricity in supramolecular solids and nano-architectures at RT

D. Asthana, A. Kumar, A. Pathak, P. K. Sukul, S. Malik, R. Chatterjee, S. Patnaik, K. Risannen, P.  Mukhopadhyay*

Chem. Commun. 2011, 47, 8928-8930.

https://doi.org/10.1039/C1CC12398J

24. Single-electron transfer driven cyanide sensing: a new multimodal approach

M. R. Ajayakumar, S. Yadav, S. Ghosh, P. Mukhopadhyay*

Org. lett. 2010, 12, 2646-2649.

https://doi.org/10.1021/ol1008558

23. Regulation of a Real‐Time Self‐Healing Process in Organogel Tissues by Molecular Adhesives

P. Mukhopadhyay*, N. Fujita*, A. Takada, T. Kishida, M. Shirakawa, S. Shinkai*

Angew. Chem. Int. Ed. 2010, 49, 6338-6342.

https://doi.org/10.1002/anie.201001382

22. Deconvolution of a multi-component interaction network using systems chemistry

S. Ghosh, P. Mukhopadhyay, L. Isaacs

Journal of Systems Chem. 2010, 1, 6.

21.Naphthalene-bis-hydrazimide: radical anions and ICT as new bimodal probes for differential sensing    of a library of amines

        M. R. Ajayakumar, P. Mukhopadhyay*

       Chem. Commun. 2009, 3702-3704 (Cover Article).

20. Reconfigurable four-component molecular switch based on pH-controlled guest swapping

S. Chakrabarti, P. Mukhopadhyay, S. Lin, L. Isaacs*

Org. lett. 2007, 9, 2349-2352.

19. Creation of 1D [60] fullerene superstructures and its polymerization by γ-ray irradiation

S. Malik, N. Fujita, P. Mukhopadhyay, Y. Goto, K. Kaneko, T. Ikeda, S. Shinkai

J. Mater. Chem. 2007, 17, 2454-2458.

18. High fidelity kinetic self-sorting in multi-component systems based on guests with multiple binding epitopes

 P. Mukhopadhyay, P. Y. Zavalij, L. Isaacs*

J. Am. Chem. Soc. 2006, 128, 14093-14102.

17. Spontaneous colorimetric sensing of the positional isomers of dihydroxynaphthalene in a 1D organogel matrix

 P. Mukhopadhyay, Y. Iwashita, M. Shirakawa, S. Kawano, N. Fujita, S. Shinkai*

Angew. Chem. 2006, 118, 1622-1625.

16. Fluorescence signaling systems with a cryptand receptor incorporating electron-withdrawing groups: Metal ion specificity and solvent dependence

B. Bag, P. Mukhopadhyay, P. K. Bharadwaj*

J. Photochem. Photobiol. A: Chemistry. 2006, 181, 215-225.

15.  Recent development of organogels towards smart and soft materials

N. Fujita, P. Mukhopadhyay, S. Shinkai*

Annual Review of Nano Research, 2006, 385-428.

14. coordination and translocation of metal ions in laterally non-symmetric aza cryptands

B. Bag, P. Mukhopadhyay, P. K. Bharadwaj*

Current Science, 2006, 1166- Exocyclic 1175 

13. Recognition properties of naphthalenediimide organogel

N. Fujita, P. Mukhopadhyay*, M. Shirakawa, Y. Iwashita, S. –i. Kawano, S. Shinkai*

55th Society of Polymer Science Japan Symposium on Macromolecules, 2006, 2689-2690.

12. the binding selectivity of the cucurbit [n] uril family

S. M Liu, C. Ruspic, J. Lagona, P. Mukhopadhyay, P.Y. Zavalij, L. Isaacs

Abstracts of papers of the American Chemical Society, 2005, 230, U3303-U3303.

On

11. The Cucurbit[n]uril Family

J. Lagona, P. Mukhopadhyay, S. Chakrabarti, L. Isaacs*

Angew. Chem. Int. Ed. 2005, 44, 4844-4870. 

10.The cucurbit [n] uril family: prime components for self-sorting systems

S. Liu, C. Ruspic, P. Mukhopadhyay*, S. Chakrabarti, P. Y. Zavalij, L. Isaacs*

J. Am. Chem. Soc. 2005, 127, 15959-15967.

9. Social self-sorting in aqueous solution

P. Mukhopadhyay, A. Wu, L. Isaacs*

J. Org. Chem. 2004, 69, 6157-6164.

8. Molecular clips form isostructural dimeric aggregates from benzene to water

A. Wu, P. Mukhopadhyay, A. Chakraborty, J. C. Fettinger, L. Isaacs*

J. Am. Chem. Soc. 2004, 126, 10035-10043.

7. Modulation of SHG responses via supramolecular association/dissociation between two complementary cryptands

P. Mukhopadhyay, P. K. Bharadwaj, A. Krishnan, P. K. Das

J. Organometallic Chem. 2004, 689, 4877-4881.

6. Laterally non-symmetric aza-cryptands: synthesis, catalysis and derivatization to new receptors

    B. Sarkar, P. Mukhopadhyay, P. K. Bharadwaj

Coord. Chem. Rev. 2003, 236, 1-13. 

5. Metal binding characteristics of a laterally nonsymmetric aza cryptand upon functionalization with a π-acceptor group

P. Mukhopadhyay, B. Sarkar, P. K. Bharadwaj, K. Nättinen, K. Rissanen

Inorg. Chem. 2003, 42, 4955-4960.

4. Binding of nitrate anion in a supramolecularly constructed macrocycle

P. Mukhopadhyay, R. J. Butcher, P. K. Bharadwaj,

Indian J. Chem. A. 2003, 42A, 2316-2319.

3. A new class of three dimensional D–π–A trigonal cryptand derivatives for second-order nonlinear optics

P. Mukhopadhyay, P. K. Bharadwaj, G. Savitha, A. Krishnan, P. K. Das

J. Mater. Chem. 2002, 12, 2237-2244.

2. Synthesis and characterization of mono-and bis-D–π–A cryptand derivatives for second-order NLO and its Modulation with different metal ions

P. Mukhopadhyay, P. K. Bharadwaj, A. Krishnan, P. K. Das

J. Mater. Chem. 2002, 12, 2786-2791.

1. The first D–π–A octupolar cryptand molecule to exhibit bulk non-linearity

P. Mukhopadhyay, P. K. Bharadwaj, G. Savitha, A. Krishnan, P. K. Das

Chem. Commun. 2000, 1815-1816.

List of Patents filed and granted in India and Abroad:

1. Method of screening anti-plasmodial activity of acriflavin and acriflavin as an anti-malarial agent,

S. K. Dhar, S. Dana, A. Dar, D. Prusty, P. Mukhopadhyay, US Patent 9,375,426.

2 Fibrous fullerene, fibrous fullerene polymer, and their manufacture by using sublimable solvent,,

N. Fujita, S. Malik, P. Mukhopadhyay, S. Shinkai,

Jpn. Kokai Tokkyo Koho (2008), JP 2008150249 A 20080703.

List of books/reviews authored:

1 Functional Molecular and Supramolecular Materials for Electron Transfer Reactions and their Applications

S. K. Keshri, S. Dana, M. R. Ajayakumar, D. Asthana, P. Mukhopadhyay

Chapter 4, Monographs in Supramolecular Chemistry No. 22.

Functional Supramolecular Materials: From Surfaces to MOFs, RSC 2017.

2. A developmental journey from first through second generations of organogels in Bottom-Up Nanofabrication,

 P. Mukhopadhyay, S. -I. Kawano, N. Fujita, S. Shinkai

2009, Chapter 55, American Scientific Publishers, Edited by Katsuhiko Ariga, K.; Nalwa, H. S.

3. Recent developments of organogels towards smart and soft materials,

N. Fujita, P. Mukhopadhyay, S. Shinkai.

2006, Chapter 9, World Scientific.

Edited by: Guozhong Cao and C. Jeffrey Brinker.

4. Electron-poor arylenediimides

S. Kumar, J. Shukla, Y. Kumar, P. Mukhopadhyay *

Org. Chem. Front. 2018, 5, 2254-2276. (Invited Review).

5. Recent Advances in Organic Radicals and Their Magnetism

S. Kumar, Y. Kumar, S. K. Keshri, P. Mukhopadhyay *

Magnetochemistry, 2016, 2, 42 (Invited Review).

6. The Cucurbit[n]uril Family

J. Lagona, P. Mukhopadhyay, S. Chakrabarti, L. Isaacs *

Angew. Chem. Int. Ed. 2005, 44, 4844-4870